This thesis deals with strongly luminescent lanthanide complexes having novel coordination structures. Luminescent lanthanide complexes are promising candidates as active materials for EL devices, lasers, and bio-sensing applications. The organic ligands in lanthanide complexes control geometrical and vibrational frequency structures that are closely related to the luminescent properties. In most of the previous work, however, lanthanide complexes have high-vibrational frequency C-H units close to the metal center for radiationless transition. In this thesis, the luminescent properties of lanthanide complexes with low-vibrational frequency C-F and P=O units are elucidated in terms of geometrical, vibrational, and chemical structures. The author also describes lanthanide coordination polymers with both high thermal stability (decomposition point > 300°C) and strong-luminescent properties (emission quantum yield > 80%). The author believes that novel studies on the characteristic structures and photophysical properties of lanthanide complexes may open up a frontier field in photophysical, coordination and material chemistry.
| ISBN: | 9784431563983 |
| Publication date: | 3rd September 2016 |
| Author: | Kohei Miyata |
| Publisher: | Springer an imprint of Springer Japan |
| Format: | Paperback |
| Pagination: | 91 pages |
| Series: | Springer Theses |
| Genres: |
Inorganic chemistry Engineering applications of electronic, magnetic, optical materials Physical chemistry |
This thesis deals with strongly luminescent lanthanide complexes having novel coordination structures. Luminescent lanthanide complexes are promising candidates as active materials for EL devices, lasers, and bio-sensing applications. The organic ligands in lanthanide complexes control geometrical and vibrational frequency structures that are closely related to the luminescent properties. In most of the previous work, however, lanthanide complexes have high-vibrational frequency C-H units close to the metal center for radiationless transition. In this thesis, the luminescent properties of lanthanide complexes with low-vibrational frequency C-F and P=O units are elucidated in terms of geometrical, vibrational, and chemical structures. The author also describes lanthanide coordination polymers with both high thermal stability (decomposition point > 300°C) and strong-luminescent properties (emission quantum yield > 80%). The author believes that novel studies on the characteristic structures and photophysical properties of lanthanide complexes may open up a frontier field in photophysical, coordination and material chemistry.
Highly Luminescent Lanthanide Complexes With Specific Coordination Structures features in the following genres: Inorganic chemistry, Engineering applications of electronic, magnetic, optical materials, Physical chemistry
Highly Luminescent Lanthanide Complexes With Specific Coordination Structures is available in Paperback, Hardback
Highly Luminescent Lanthanide Complexes With Specific Coordination Structures was written by Kohei Miyata and published by Springer an imprint of Springer Japan
Highly Luminescent Lanthanide Complexes With Specific Coordination Structures has 91 pages
Yes it is part of Springer Theses series