Iron catalysts in organic synthesis are strongly in demand because iron is non-toxic, inexpensive and the most abundant transition metal in the earth, although their use is still limited compared with that of rare, precious metals such as palladium, ruthenium and rhodium. This thesis describes the first practical example of iron catalysis in the carbon-hydrogen bond activation reaction to synthesized fused aromatic ring compounds. By using a unique combination of iron catalyst and dichloride oxidant, various kind of naphthalene and phenanthrene derivatives were synthesized via annulation reaction with alkynes including direct C-H bond activation process. This achievement opens the new possibility of low-valent iron catalysis and expands synthetic methods for a sustainable society.
| ISBN: | 9784431549277 |
| Publication date: | 25th July 2014 |
| Author: | Arimasa Matsumoto |
| Publisher: | Springer an imprint of Springer Japan |
| Format: | Hardback |
| Pagination: | 74 pages |
| Series: | Springer Theses |
| Genres: |
Organometallic chemistry Materials science |
Iron catalysts in organic synthesis are strongly in demand because iron is non-toxic, inexpensive and the most abundant transition metal in the earth, although their use is still limited compared with that of rare, precious metals such as palladium, ruthenium and rhodium. This thesis describes the first practical example of iron catalysis in the carbon-hydrogen bond activation reaction to synthesized fused aromatic ring compounds. By using a unique combination of iron catalyst and dichloride oxidant, various kind of naphthalene and phenanthrene derivatives were synthesized via annulation reaction with alkynes including direct C-H bond activation process. This achievement opens the new possibility of low-valent iron catalysis and expands synthetic methods for a sustainable society.
Iron-Catalyzed Synthesis of Fused Aromatic Compounds Via C-H Bond Activation features in the following genres: Organometallic chemistry, Materials science
Iron-Catalyzed Synthesis of Fused Aromatic Compounds Via C-H Bond Activation is available in Hardback
Iron-Catalyzed Synthesis of Fused Aromatic Compounds Via C-H Bond Activation was written by Arimasa Matsumoto and published by Springer an imprint of Springer Japan
Iron-Catalyzed Synthesis of Fused Aromatic Compounds Via C-H Bond Activation has 74 pages
Yes it is part of Springer Theses series