This thesis offers novel methods for catalyst and process design for the selective hydrogenation of acetylene and 1,3-butadiene. The author predicts the properties of supported Pd-Ni bimetallic catalysts using density functional theory (DFT) calculations and temperature-programmed desorption (TPD). The excellent correlation between model surfaces and supported catalysts demonstrates the feasibility of designing effective bimetallic catalysts for selective hydrogenation reactions. The author also proposes a method for designing non-precious metal catalysts to replace precious metals. She modifies the process of selective hydrogenation of acetylene by coupling the selective adsorption to the selective hydrogenation in the liquid phase, as a result of which the ethylene selectivity is greatly improved and heat transfer is greatly enhanced. Lastly, by analyzing the mechanism of liquid-phase hydrogenation, the author proposes a multi-stage slurry bed reactor for industrial applications.<
| ISBN: | 9789811007729 |
| Publication date: | 12th January 2017 |
| Author: | Ruijun Hou |
| Publisher: | Springer an imprint of Springer Nature Singapore |
| Format: | Hardback |
| Pagination: | 141 pages |
| Series: | Springer Theses |
| Genres: |
Catalysis Quantum and theoretical chemistry Industrial chemistry and chemical engineering Organic chemistry |
This thesis offers novel methods for catalyst and process design for the selective hydrogenation of acetylene and 1,3-butadiene. The author predicts the properties of supported Pd-Ni bimetallic catalysts using density functional theory (DFT) calculations and temperature-programmed desorption (TPD). The excellent correlation between model surfaces and supported catalysts demonstrates the feasibility of designing effective bimetallic catalysts for selective hydrogenation reactions. The author also proposes a method for designing non-precious metal catalysts to replace precious metals. She modifies the process of selective hydrogenation of acetylene by coupling the selective adsorption to the selective hydrogenation in the liquid phase, as a result of which the ethylene selectivity is greatly improved and heat transfer is greatly enhanced. Lastly, by analyzing the mechanism of liquid-phase hydrogenation, the author proposes a multi-stage slurry bed reactor for industrial applications.<
Catalytic and Process Study of the Selective Hydrogenation of Acetylene and 1,3-Butadiene features in the following genres: Catalysis, Quantum and theoretical chemistry, Industrial chemistry and chemical engineering, Organic chemistry
Catalytic and Process Study of the Selective Hydrogenation of Acetylene and 1,3-Butadiene is available in Hardback
Catalytic and Process Study of the Selective Hydrogenation of Acetylene and 1,3-Butadiene was written by Ruijun Hou and published by Springer an imprint of Springer Nature Singapore
Catalytic and Process Study of the Selective Hydrogenation of Acetylene and 1,3-Butadiene has 141 pages
Yes it is part of Springer Theses series