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Single-Ion Solvation Experimental and Theoretical Approaches to Elusive Thermodynamic Quantities

by Philippe H. Hunenberger, Maria M. Reif

Part of the Theoretical and Computational Chemistry Series Series

Single-Ion Solvation Experimental and Theoretical Approaches to Elusive Thermodynamic Quantities Synopsis

Ions are ubiquitous in chemical, technological, ecological and biological processes. Characterizing their role in these processes in the first place requires the evaluation of the thermodynamic parameters associated with the solvation of a given ion. However, due to the constraint of electroneutrality, the involvement of surface effects and the ambiguous connection between microscopic and macroscopic descriptions, the determination of single-ion solvation properties via both experimental and theoretical approaches has turned out to be a very difficult and highly controversial problem. This unique book provides an up-to-date, compact and consistent account of the research field of single-ion solvation thermodynamics that has over one hundred years of history and still remains largely unsolved. By reviewing the various approaches employed to date, establishing the relevant connections between single-ion thermodynamics and electrochemistry, resolving conceptual ambiguities, and giving an exhaustive data compilation (in the context of alkali and halide hydration), this book provides a consistent synthesis, in depth understanding and clarification of a large and sometimes very confusing research field. The book is primarily aimed at researchers (professors, postgraduates, graduates, and industrial researchers) concerned with processes involving ionic solvation properties (these are ubiquitous, eg. in physical/organic/analytical chemistry, electrochemistry, biochemistry, pharmacology, geology, and ecology). Because of the concept definitions and data compilations it contains, it is also a useful reference book to have in a university library. Finally, it may be of general interest to anyone wanting to learn more about ions and solvation. Key features: - discusses both experimental and theoretical approaches, and establishes the connection between them - provides both an account of the past research (covering over one hundred years) and a discussion of current directions (in particular on the theoretical side) - involves a comprehensive reference list of over 2000 citations - employs a very consistent notation (including table of symbols and unambiguous definitions of all introduced quantities) - provides a discussion and clarification of ambiguous concepts (ie. concepts that have not been defined clearly, or have been defined differently by different authors, leading to confusion in past literature) - encompasses an exhaustive data compilation (in the restricted context of alkali and halide hydration), along with recommended values (after critical analysis of this literature data) - is illustrated by a number of synoptic colour figures, that will help the reader to grasp the connections between different concepts in one single picture

Single-Ion Solvation Experimental and Theoretical Approaches to Elusive Thermodynamic Quantities Press Reviews

'This book gives a comprehensive survey of principles, theory and experimental aspects of single ion solvation.''the authors make extensive use of numbered lists of points. I found that this type of presentation works well.''It is this combination of comprehensive lists and personal recommendations that will make the book particularly valuable.''I recommend this book to all those who use ions and hope that it will be purchased by every chemistry research library.' * Ruth Lynden-Bell * offers the best discussion I've seen of the subject's complexities and subtleties. The book's careful explanations should make its readers much more comfortable in tackling the thorny issues It is hard to overemphasize the high quality of the writing * Donald G Truhlar *

Book Information

ISBN: 9781847551870
Publication date: 14th April 2011
Author: Philippe H. Hunenberger, Maria M. Reif
Publisher: Royal Society of Chemistry
Format: Hardback
Pagination: 690 pages
Categories: Quantum & theoretical chemistry,

About Philippe H. Hunenberger, Maria M. Reif

Philippe Hunenberger, previously Assistant Professor, is now a Senior Scientist at the Institute of Physical Chemistry, ETH Zurich (ETHZ). He completed his undergraduate studies at the University of Lausanne and his PhD at ETHZ followed by a period of time at UCSD, San Diego as a post-doctoral fellow. He has received numerous undergraduate and graduate awards including the Ruzicka Prize in 2008 and has been awarded a number of research grants. With countless published papers and oral presentations at key international conferences, he is regarded as a world renowned expert in his field. Maria Reif is at the Institute of Physical ...

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